We propose a Bayesian Penalized Spline Predictive (BPSP) estimator for a finite population proportion in an unequal probability sampling setting. This new method allows the probabilities of inclusion to be directly incorporated into the estimation of a population proportion, using a probit regression of the binary outcome on the penalized spline of the inclusion probabilities. The posterior predictive distribution of the population proportion is obtained using Gibbs sampling. The advantages of the BPSP estimator over the Hájek (HK), Generalized Regression (GR), and parametric model-based prediction estimators are demonstrated by simulation studies and a real example in tax auditing. Simulation studies show that the BPSP estimator is more efficient, and its 95% credible interval provides better confidence coverage with shorter average width than the HK and GR estimators, especially when the population proportion is close to zero or one or when the sample is small. Compared to linear model-based predictive estimators, the BPSP estimators are robust to model misspecification and influential observations in the sample.